These pictures are Jessica Simpson in 1999 and again in 2007.
The doc says that she most certainly had an eye-lift between then and now and has also had her nose shaved down a smidge. I dunno about the nose, but I definitely think her eyes look way bigger. There was also a pic of her boobs from way back when, but I'm not even gonna go there.
"Dr. Hollywood" says that she's definitely had a nose job. I agree. It looks like it shrunk quite a bit. I'm pretty sure that noses don't get smaller as you get older. My grandma once told me that the two parts of your face that grow the fastest are your ears and your nose. This was not a good thing to tell a 13-year-old who was VERY self-conscious about her nose at the time. However, Angelina's genes must be ones of the shrinking variety. I see that her lips have been reeled in a bit as well.
I'm no doctor, but I'd say something un-natural has been going on here.